It is not recommended to talk while answering the call of nature.

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If you are giving it to the poor, it is charity. If you are donating it, it depends on the projects.

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There is nothing as such.

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Asma bint Yazeed said: “The Messenger of Allah (peace and blessings of Allah be upon him) said: ‘Lying is not permitted except in three cases: a man’s speaking to his wife to make her happy; lying at times of war; and lying in order to reconcile between people.’” (Tirmidhi, 1862)

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This is permissible but not recommended

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