There isn’t anything specific. She should ask whatever she wants from Allah.

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One can make general invocation and thikr to Allah as well as general Du’ah.

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Morning is after fajr but evening is an issue of dispute. Some scholars say after Asr and others say after Maghrib. I take this last opinion.

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I know that whoever recites this supplication, Allah will relieve him from his depression and calamity. I don’t know about the 3 times as I don’t believe that it is part of the Sunnah.

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There is a hadeeth that recommended making Du’ah while raining.

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