ANSWER:

It is totally prohibited for anyone to pray before the time for salah has entered whether before or after the athan! But if the time is due and the athan is delayed, she can pray. 

Is it permissible for women to pray fard salah before adhan?

Prayer | March 2, 2018 7:01 am
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I wear loose trousers and shirt at home and there is only my husband at home. Can I pray my salah with this outfit at home when there is no one around?